| 分光光度法测定高纯度膨润土吸蓝量 |
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| 引用本文： | 黄丽,;高倩倩,;蔡延平,;董清木,;刘海波.分光光度法测定高纯度膨润土吸蓝量[J].化学分析计量,2014(2):17-19. |
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| 作者姓名： | 黄丽 ;高倩倩 ;蔡延平 ;董清木 ;刘海波 |
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| 作者单位： | [1]厦门大学化学化工学院,福建厦门 361005; [2]厦门出入境检验检疫局,福建厦门 361005; [3]厦门紫金矿冶技术有限公司,福建厦门361101 |
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| 基金项目： | 国家质检总局科技计划项目（2014IK254） |
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| 摘 要： | 以分光光度法测定高含量膨润土吸蓝量,应用正交试验设计对分光光度法的实验条件进行优化,确定的最佳实验条件:煮沸时间为5 min,4%焦磷酸钠溶液加入体积为20 mL,0.01 mol/L亚甲基蓝溶液加入体积为30mL,振荡时间为15 min。该法与滴定法对比,测定值相对误差在4%以内,相对标准偏差为1.04%,可满足高纯度膨润土吸蓝量的分析要求。
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| 关 键 词： | 高纯度膨润土 吸蓝量 正交试验 分光光度法 |
Determination of the Methylene Blue Value of High Levels of Bentonite by Spectrophotometry |
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| Institution: | Huang Li, Gao Qianqian, Cai Yanping, Dong Qingmu, Liu Haibo ( 1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China; 2. Xiamen Entry-Exit Inspection and Quarantine Bureau, Xiamen 361005, China; 3. Xiamen Zijin Mining and Metallurgy Technology Co. Ltd., Xiamen 361101, China ) |
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| Abstract: | Spectrophotometry was used to measure the methylene blue value of high purity bentonite, and the orthogonal tests were used to optimize and determine the optimal experimental conditions：the boiling time was 5 min, 4%sodium pyrophosphate solution was added to a volume of 20 mL, 0.01 mol/L methylene blue solution was added to the volume of 30 mL, shaking time was 15 min. Compared the spectrophotometry to traditional titration analysis, the relative error of the experimental results was less than 4%and the relative standard deviation was 1.04%, which was proved to be accurate and reliable to meet the analytical requirements. |
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| Keywords: | high purity bentonite methylene blue value orthogonal tests spectrophotometry |
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