| 气相色谱-质谱联用法在火药剖析中的应用 |
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| 引用本文： | 李俊平,崔桂萍,李彩青,任洁,梁瑞红.气相色谱-质谱联用法在火药剖析中的应用[J].化学分析计量,2012,21(6):44-46. |
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| 作者姓名： | 李俊平 崔桂萍 李彩青 任洁 梁瑞红 |
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| 作者单位： | 山西北方兴安化学工业有限公司,太原,030008 |
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| 摘 要： | 采用固液萃取的方法对火药样品进行处理，用气相色谱-质谱联用法对某未知火药进行成分剖析，以选择离子质谱法进行定量。目标化合物浓度在20-50mg／L范围内与色谱峰面积呈良好的线性关系，相关系数在0．9940～0．9996之间。方法加标回收率为96．9％～104.3％，测定结果的相对标准偏差为2．4％-4．9％（n=5）.气相色谱-质谱联用法可用于火药剖析研究。
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| 关 键 词： | 气相色谱-质谱联用仪 火药 剖析 定性分析 定量分析 |
Application of Gas Chromatograph-Mass Spectrometry in Gun-Powder Analysis |
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| Li Junping
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Cui Guiping
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Li Caiqing
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Ren Jie
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Liang Ruihong.Application of Gas Chromatograph-Mass Spectrometry in Gun-Powder Analysis[J].Chemical Analysis And Meterage,2012,21(6):44-46. |
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| Authors: | Li Junping Cui Guiping Li Caiqing Ren Jie Liang Ruihong |
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| Institution: | (Shanxi North Xing’an Chemistry Industry Co.,LTD.,Taiyuan 030008,China) |
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| Abstract: | The gun-powder sample was treated by solid-liquid extraction method, the components in unknown gun-powder were anatomized by gas chromatograph-mass spectrometry. Selective ion quantitative method was used for quantitative analysis. The concentration of target compound was linear with ch＇romatographic peak area inthe range of 20-50 mg/L, the correlation coefficient was 0.994 0-0.999 6. The recovery rate was 96.9%-104.3% and relative standard deviation of analysis results was 0.4%-4.9%（n=5）. Gas chromatograph-mass spectrometry is suitable for the analysis of gun-powder anatomy research. |
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| Keywords: | gas chromatograph-mass spectrometer gun-power anatomy qualitative analysis quantitative analysis |
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