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矿物药金礞石的红外光谱分析
引用本文:王栋,刘卉,王伯涛.矿物药金礞石的红外光谱分析[J].分析测试学报,2011,30(5):577-581.
作者姓名:王栋  刘卉  王伯涛
作者单位:1.南京工业大学药学院;2.黄石市食品药品监督检验所
基金项目:“十一五”国家科技支撑计划重点资助项目(2008BAI55B00)
摘    要:采用傅立叶红外光谱法分析了金礞石试样,对所得图谱进行解析,发现试样的红外光谱具备层状硅酸盐矿物的吸收特征.其吸收带主要分为4个区域:3 700~3 000 cm-1区间的OH伸缩振动吸收,1 620 cm-1左右处的H2O弯曲振动吸收,1 000 cm-1左右处的Si-O伸缩振动吸收和550~400 cm-1区间的Si...

关 键 词:金礞石  红外光谱  矿物药

FTIR Analysis of Mineral Medicine Lapis Micae Aureus
WANG Dong,LIU Hui,WANG Bo-tao.FTIR Analysis of Mineral Medicine Lapis Micae Aureus[J].Journal of Instrumental Analysis,2011,30(5):577-581.
Authors:WANG Dong  LIU Hui  WANG Bo-tao
Institution:1(1.School of Pharmaceutical Science,Nanjing University of Technology,Nanjing 211816,China; 2.Huangshi Institute for Food and Drug Control,Huangshi 435000,China)
Abstract:FTIR was applied in the analysis of Lapis Micae Aureu samples,and the corresponding spectra were interpreted.The results indicated that the absorption characteristics of spectra of Lapis Micae Aureu samples were similar to those of the layered silicate minerals.The absorption area was divided into four regions:OH stretching vibration absorption at 3 700-3 000 cm-1,H2O bending vibration absorption at 1 620 cm-1,Si—O stretching vibration absorption at 1 000 cm-1 and Si—O bending vibration absorption at 550-400 cm-1.The results showed that,OH vibration absorption intensity was in positive proportion to water content in Lapis Micae Aureu samples and the absorption frequency was related to the type of the interlayer cation.Si—O vibration absorption frequency was affected by Al substituting Si in tetrahedroid,and the absorption frequency reflects the type of cation in octahedron.Thus the infrared spectral characteristics of Lapis Micae Aureu samples could reflect its internal structure,and could be used to evaluate its quality status.
Keywords:Lapis Micae Aureus  FTIR  mineral medicine
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