Synthesis and physicochemical properties of copolymers of aniline and 3,4-ethylenedioxythiophene |
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| Authors: | A V Kubarkov O A Pyshkina V G Sergeyev |
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| Institution: | 1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia
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| Abstract: | Copolymers of various compositions have been synthesized via copolymerization of aniline with 3,4-ethylenedioxythiophene in the presence of a poly(4-styrenesulfonic acid) matrix, and a mechanism of copolymerization has been suggested. It has been shown that the synthesized copolymers are included in non-stoichiometric interpolyelectrolyte complexes with matrices stabilized by salt bonds and nonionic interactions. The copolymers of aniline and ethylenedioxythiophene possess electrical conductivity and can enter into redox and acid-base reactions. |
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