Regioirregular ambipolar naphthalenediimide‐based alternating polymers: Synthesis,characterization, and application in field‐effect transistors |
| |
| Authors: | Weifeng Zhang Congyuan Wei Jianyao Huang Zhihui Chen Liping Wang Gui Yu |
| |
| Institution: | 1. Organic Solids Laboratory, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, People's Republic of China;2. School of Material Science and Engineering, University of Science and Technology Beijing, People's Republic of China;3. University of Chinese Academy of Sciences, Beijing, People's Republic of China |
| |
| Abstract: | In this work, we report the synthesis, characterization, and application of two regioirregular naphthalenediimide (NDI)‐based alternating conjugated polymers, namely P1 and P2 , in which nitrile‐substituted moiety, 2,3‐bis(thiophen‐2‐yl)acrylonitrile and NDI moiety act as donor and acceptor unit, respectively. The two regioirregular polymers possess low‐lying LUMO energy levels of ?3.92 eV for P1 and ?3.96 eV for P2 . Both polymers possess typical dual‐band UV?Vis?NIR absorption profiles of NDI‐based polymers, and show broadened and red‐shifted absorption spectra in the solid state compared with those in solutions. Field‐effect transistor devices with top‐gate bottom‐contact configuration were used to evaluate the polymers' semiconducting properties. The two polymers exhibited promising and air‐stable ambipolar charge transport characteristics. Thin film microstructure investigations (AFM and 2D‐GIXRD) suggest both polymers formed continuous and smooth thin films, and adopted predominantly face‐on molecular packing in the solid state. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55 , 3627–3635 |
| |
| Keywords: | ambipolar carrier transport asymmetric units field‐effect transistors naphthalenediimide polymer semiconductors |
|
|
