Effect of the initial maleic anhydride content on the grafting of maleic anhydride onto isotactic polypropylene

A series of ¹³C‐enriched maleic anhydride grafted isotactic polypropylene samples were prepared in solution at 170 °C by changes in the initial maleic anhydride content. The NMR spectra of the samples showed that the signals of the maleic anhydride attached to the tertiary carbons of the isotactic polypropylene chains increased considerably with increasing maleic anhydride content, whereas the signals of the maleic anhydride on the radical chain ends (with a single bond) arising from β scission did not. On the other hand, the signals of the maleic anhydride on the radical chain ends with double bonds increased markedly with increasing maleic anhydride content, and this suggested that β scission could occur extensively after maleic anhydride was attached to the tertiary carbons. As a result, the molecular weight of the grafted polypropylene decreased significantly with increasing maleic anhydride content in this study. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5529–5534, 2005