A novel photosynthetic mimic reaction catalysed by K[Ru(H-EDTA)Cl] · 2H2O; reduction of carbon dioxide to formate and formaldehyde in the presence of an aqueous suspension of Pt—CdS—RuO2 |
| |
Authors: | M M Taqui Khan N Nageswara Rao Debabrata Chatterjee |
| |
Institution: | Discipline of Coordination Chemistry and Homogeneous Catalysis, Central Salt and Marine Chemicals Research Institute, Bhavnagar 364 002 India |
| |
Abstract: | An efficient photocatalytic reduction of carbon dioxide to HCOOH and HCHO is reported using KRu(H-EDTA)Cl] · 2H2O (1) as homogeneous catalyst and particulate Pt—CdS—RuO2 as photon absorber at 505 nm. This system produces 0.22 M of HCOOH and 0.10 M of HCHO in 6 h of photolysis at rates of 3.05 × 10−2 M h−1 and 2.0 × 10−2 M h−1 respectively. Trace amounts of CH3OH, CH4 and CO are detected in the reaction vessel. The rates of formation of HCOOH and HCHO exhibit a first-order dependence on the catalyst and dissolved CO2 concentrations. The reaction shows deuterium isotope effects (kH/kD) of 1.5 and 2.00 for the formation of HCOOH and HCHO respectively. Under identical experimental conditions, the rate of decomposition of formate was studied. The rate of decomposition of formate is slower (by two orders of magnitude compared with the formation of formate) even at high formate concentrations. A mechanism for the formation of HCOOH and HCHO is proposed. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |