| 新型苝酰亚胺衍生物的合成及其光学性能 |
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| 引用本文： | 杜斌,余建华,李志军,丁志军.新型苝酰亚胺衍生物的合成及其光学性能[J].合成化学,2012,20(4):421-424,429. |
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| 作者姓名： | 杜斌 余建华 李志军 丁志军 |
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| 作者单位： | 防化研究院,北京,102205 |
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| 基金项目： | 国家重点基础研究发展计划(973)资助项目 |
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| 摘 要： | 以3,4,9,10-苝四酸二酐为原料,设计并合成了三个新型的苝酰亚胺衍生物———N,N’-二(1-戊基己基)-3,4,9,10-苝四羧酸二酰亚胺,N,N’-二(1-戊基己基)-1,6,7,12-四(对叔丁基苯氧基)-3,4,9,10-苝四羧酸二酰亚胺和N,N’-二(4-六氟异丙醇基苯基)-1,6,7,12-四(对叔丁基苯氧基)-3,4,9,10-苝四羧酸二酰亚胺,其结构经1H NMR和MS表征。用UV-Vis和荧光光谱研究了他们的光学性质。
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| 关 键 词： | 苝四酸二酐 苝酰亚胺 合成 光学性质 |
Synthesis and Optical Properties of Novel Perylene Diimide Derivatives |
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| DU Bin
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YU Jian-hua
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LI Zhi-jun
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DING Zhi-jun.Synthesis and Optical Properties of Novel Perylene Diimide Derivatives[J].Chinese Journal of Synthetic Chemistry,2012,20(4):421-424,429. |
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| Authors: | DU Bin YU Jian-hua LI Zhi-jun DING Zhi-jun |
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| Institution: | (Research Institute of Chemical Defense,Beijing 102205,China) |
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| Abstract: | Three novel perylene diimide derivatives,N,N′-di(1-pentylhexyl)-perylene-3,4,9,10-tertracarboxylic acid diimide,N,N′-di(1-pentylhexyl)-1,6,7,12-tetra(4-t-butylphenoxy)-perylene-3,4,9,10-tertracarboxylic acid diimide and N,N′-di(4-hexafluoroisopropanol phenyl)-1,6,7,12-tetra(4-t-butylphenoxy)-perylene-3,4,9,10-tertracarboxylic acid diimide,were synthesized from 3,4,9,10-perylenetetracarboxylic dianhydride.The structures were characterized by 1H NMR and MS.The optical properties of them were investigated by UV-Vis and fluorescence spectrum. |
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| Keywords: | perylenetetracarboxylic dianhydride perylene diimide synthesis optical property |
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