| 具有光引发活性RAFT链转移剂的合成与应用 |
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| 引用本文： | 刘忠彬,程传杰,申亮,郑义.具有光引发活性RAFT链转移剂的合成与应用[J].合成化学,2012,20(1):104-106. |
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| 作者姓名： | 刘忠彬 程传杰 申亮 郑义 |
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| 作者单位： | 江西科技师范学院江西省有机功能分子重点实验室,江西南昌,330013 |
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| 基金项目： | 国家自然科学基金，江西省自然科学基金 |
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| 摘 要： | 以4-溴甲基二苯甲酮,3-巯基丙酸和二硫化碳为原料合成了RAFT链转移剂——3-(4-苯甲酰基苯基甲硫基硫代羰基硫基)丙酸(2),产率91.5%,其结构经NMR,IR和元素分析表征。以2为RAFT链转移剂和光引发剂,通过甲基丙烯酸烯丙酯的乳液聚合制得反应性聚甲基丙烯酸烯丙酯。
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| 关 键 词： | RAFT链转移剂 光引发剂 二苯甲酮 反应性聚甲基丙烯酸烯丙酯 合成 应用 |
Synthesis and Application of RAFT Chain Transfer Agent with Photoinitiating Activity |
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| LIU Zhong-bin
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CHENG Chuan-jie
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SHEN Liang
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ZHENG Yi.Synthesis and Application of RAFT Chain Transfer Agent with Photoinitiating Activity[J].Chinese Journal of Synthetic Chemistry,2012,20(1):104-106. |
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| Authors: | LIU Zhong-bin CHENG Chuan-jie SHEN Liang ZHENG Yi |
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| Institution: | (Jiangxi Key Lab of Organic Chemistry,Jiangxi Science Technology Normal University,Nanchang 330013,China) |
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| Abstract: | A RAFT chain transfer agent with photoinitiating activity,3-(4-benzoylbenzylsulfanylthiocarbonylsufanyl)propionic acid(2),was synthesized from 4-bromomethylbenzophenone,3-mercaptopropionic acid and carbon disulfide in 91.5% yield.The structure was characterized by NMR,IR and elemental analysis.Reactive poly(allyl methacrylate) was prepared using 2 as the RAFT chain transfer agent and photoinitiator by emulsion polymerization of allyl methacrylate. |
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| Keywords: | RAFT chain transfer agent photoinitiator benzophenone poly(allyl methacrylate) synthesis application |
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