| 新型树枝状分子3,5-二[3,5-二(4-羧基苯甲氧基)苯甲氧基]苯甲醇的合成 |
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| 引用本文： | 刘静,彭亦如,张宏,吴克勤,陈莉莉,阙寿林,陈奎治,陈燕燕,陈婉玲.新型树枝状分子3,5-二[3,5-二(4-羧基苯甲氧基)苯甲氧基]苯甲醇的合成[J].合成化学,2012,20(1):52-55. |
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| 作者姓名： | 刘静 彭亦如 张宏 吴克勤 陈莉莉 阙寿林 陈奎治 陈燕燕 陈婉玲 |
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| 作者单位： | 福建师范大学化学与材料学院福建省高分子材料重点实验室,福建福州,350007 |
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| 基金项目： | 国家自然科学基金，卫生部科学研究基金金资助项目，福建省自然科学基金金资助项目，福建省科技厅重点资助项目，福建省大学生创新性实验计划资助项目 |
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| 摘 要： | 采用收敛法,以对氰基苄溴和3,5-二羟基苯甲醇为原料,依次合成了端基为腈基的芳醚树枝状分子3,5-二(4-腈基苯甲氧基)苯甲醇(4)和3,5-二3,5-二(4-腈基苯甲氧基)苯甲氧基]苯甲醇(6)；4与6分别经水解制得以羧基为端基的新型芳基苄醚树枝状分子3,5-二(4-羧基苯甲氧基)苯甲醇和3,5-二3,5-二(4-羧基苯甲氧基)苯甲氧基]苯甲醇,其结构经UV-Vis,1H NMR,IR,MS和元素分析表征.
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| 关 键 词： | 树枝状分子 对氰基苄溴 3 5-二羟基苯甲醇 收敛法 合成 |
Synthesis of Novel Dendritic Compound 3,5-Di[ 3,5-di ( 4-carboxyl benzyloxy) benzyloxy ] benzyl Alcohol |
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| LIU Jing
,
PENG Yi-ru
,
ZHANG Hong
,
WU Ke-qing
,
CHEN Li-li
,
QUE Shou-lin
,
CHEN Kui-zhi
,
CHEN Yan-yan
,
CHEN Wan-ling.Synthesis of Novel Dendritic Compound 3,5-Di[ 3,5-di ( 4-carboxyl benzyloxy) benzyloxy ] benzyl Alcohol[J].Chinese Journal of Synthetic Chemistry,2012,20(1):52-55. |
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| Authors: | LIU Jing PENG Yi-ru ZHANG Hong WU Ke-qing CHEN Li-li QUE Shou-lin CHEN Kui-zhi CHEN Yan-yan CHEN Wan-ling |
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| Institution: | (Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China) |
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| Abstract: | 3,5-di(4-cyano benzyloxy)benzyl alcohol(4) and 3,5-di3,5-di(4-cyano benzyloxy) benzyloxy]benzyl alcohol(6) were synthesized in turn by convergent growth method from 4-(bromomethyl)benzonitrile and 3,5-dihydroxybenzyl alcohol.Two novel carboxyl-terminated dendrons,3,5-di(4-carboxyl benzyloxy)benzyl alcohol and 3,5-di3,5-di(4-carboxyl benzyloxy)benzyloxy]benzyl alcohol,were prepared by the hydrolysis from 4 and 6,respectively.The structures were characterized by UV-Vis,1H NMR,IR,MS and elemental analysis. |
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| Keywords: | dendrimer 4-(bromomethyl)benzonitrile 3 5-dihydroxybenzyl alcohol convergent growth method synthesis |
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