| 含茂基及双乙酰丙酮缩乙二胺基稀土金属有机配合物的合成及表征 |
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| 引用本文： | 张武,蔡跃鹏.含茂基及双乙酰丙酮缩乙二胺基稀土金属有机配合物的合成及表征[J].合成化学,1999,7(2):112-114. |
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| 作者姓名： | 张武 蔡跃鹏 |
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| 作者单位： | 安徽师范大学有机化学研究所 |
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| 摘 要： | 由双乙酰丙酮缩乙二胺与三茂稀土在四氢呋喃溶液中室温下反应，合成了具有通式为（ａｃｅｎ）ＬｎＣｐ（Ｃｐ＝η＾５－Ｃ５Ｈ５，Ｌｎ＝Ｙ，Ｎｄ，Ｔｂ，Ｄｙ，Ｅｒ，Ｙｂ）的６个新稀土金属有机配合物，这些配合物均经元素分析，ＩＲ，ＭＳ和＾１Ｈ ＮＭＲ表征。
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| 关 键 词： | 稀土 配合物 双乙酰丙酮缩 乙二胺 合成 |
Synthesis and Characterization of Monocyclopentadienyl Rare Earth() Derivatives ContainingN, Ndiacetylacetoneethylenediamine |
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| Zhang,WuCai,YuePengMa,HuaiZhu.Synthesis and Characterization of Monocyclopentadienyl Rare Earth() Derivatives ContainingN, Ndiacetylacetoneethylenediamine[J].Chinese Journal of Synthetic Chemistry,1999,7(2):112-114. |
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| Authors: | Zhang WuCai YuePengMa HuaiZhu |
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| Abstract: | Six new rare earth organometallic complexes (Ln=Y,Nd,Tb,Dy,Er,Yb; Cp=Cyclopentadienyl; acen=N,Ndiacetylacetoneethylenediaminato dianion) were synthesized by the reaction of Cp3Ln with H2acen. All the complexes were characterized by elemental analyses, IR, MS and 1H NMR spectra. |
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| Keywords: | Rare earth Organometallic complexes N Ndiacetylacetoneethylenediamine Synthesis |
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