| 苄连氮桥联双硫杂杯[4]芳烃的合成 |
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| 引用本文： | 赵夏,杨发福.苄连氮桥联双硫杂杯[4]芳烃的合成[J].合成化学,2009,17(2). |
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| 作者姓名： | 赵夏 杨发福 |
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| 作者单位： | 1. 银川大学,石油化工学院,宁夏,银川,750105
2. 福建师范大学,化学与材料学院,福建,福州,350007 |
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| 基金项目： | 国家自然科学基金，福建省自然科学基金，宁夏高等学校科研资助项目 |
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| 摘 要： | 硫杂杯4]二醛基衍生物(1)在水合肼中肼解,合成了新化合物硫杂杯4]二醛腙基衍生物(2);1和2在弱酸的催化下反应合成了新的具有对称结构的苄连氮双硫杂杯4]芳烃(3);2和3的结构经1H NMR,IR,ESI-MS和元素分析表征.
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| 关 键 词： | 双硫杂杯[4]芳烃 苄连氮基 合成 |
Synthesis of Benzalazine-Bridged Bisthiacalix[4] arene |
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| ZHAO Xia,YANG Fa-fu.Synthesis of Benzalazine-Bridged Bisthiacalix[4] arene[J].Chinese Journal of Synthetic Chemistry,2009,17(2). |
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| Authors: | ZHAO Xia YANG Fa-fu |
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| Institution: | 1.College of Petrochemical Technology;Yinchuan Normal University;Yinchuan 750105;China;2.College of Chemistry and Materials;Fujian Normal University;Fuzhou 350007;China |
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| Abstract: | A new thiacalix4]arene hydrazone derivative(2) was synthesized by the reaction of thiacalix4]arene bi-benzaldehyde derivative(1) with hydrazine hydrate.A novel benzalazine-bridged bisthiacalix4]arene(3) was obtained by the reaction of 1 with 2 using weak acid as a catalyst.The structures of 2 and 3 were characterized by 1H NMR,IR,ESI-MS and elemental analysis. |
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| Keywords: | bisthiacalix[4]arene benzalazine synthesis |
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