| 反式-6-对氟苯乙烯基吲哚的合成 |
| |
| 引用本文： | 戴红,葛裕华.反式-6-对氟苯乙烯基吲哚的合成[J].合成化学,2006,14(4):384-385,391. |
| |
| 作者姓名： | 戴红 葛裕华 |
| |
| 作者单位： | 东南大学化学化工系 江苏南京210096 |
| |
| 摘 要： | 对氟氯化苄和三苯基膦在氯仿中回流制得对氟氯化苄基三苯基鏻盐(1),1与吲哚-6-甲醛在EtONa存在下通过Wittig反应合成了新的反式-6-对氟苯乙烯基吲哚(2),其结构经1H NMR,IR,MS和元素分析确证。荧光分析表明,2具有荧光性能。
|
| 关 键 词： | 吲哚-6-甲醛 Wittig反应 苯乙烯基吲哚 合成 |
| 文章编号： | 1005-1511（2006）04-0384-02 |
| 收稿时间： | 2006-02-26 |
| 修稿时间： | 2006-02-26 |
Synthesis of Trans-6-(p-fluorophenyl)vinylindole |
| |
| DAI Hong, GE Yu-hua.Synthesis of Trans-6-(p-fluorophenyl)vinylindole[J].Chinese Journal of Synthetic Chemistry,2006,14(4):384-385,391. |
| |
| Authors: | DAI Hong GE Yu-hua |
| |
| Institution: | Department of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, China |
| |
| Abstract: | A new compound,trans-6-(p-fluorophenyl)vinylindole(2),was synthesized from (p-fluoro)benzyl]triphenylphosphonium chloride(1) and indole-6-formaldehyde by Wittig reaction in the presence of EtONa.1 was obtained from p-fluorobenzyl chloride and triphenyl phosphine.The structure of 2 was confirmed by ~1H NMR,IR,MS and elemental analysis.2 exhibits fluorescence by fluorescent analysis. |
| |
| Keywords: | indole-6-formaldehyde styrylindole Wittig reaction synthesis fluorescence |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
