| 基于3,5-吡啶二羧酸和双咪唑配体构筑的锌(Ⅱ)配位聚合物的合成、晶体结构及其荧光性质 |
| |
| 引用本文： | 王莉,李少华,王瑞雪,李楠楠,刘斌,袁粉粉,王帅,闫彬.基于3,5-吡啶二羧酸和双咪唑配体构筑的锌(Ⅱ)配位聚合物的合成、晶体结构及其荧光性质[J].合成化学,2017(1). |
| |
| 作者姓名： | 王莉 李少华 王瑞雪 李楠楠 刘斌 袁粉粉 王帅 闫彬 |
| |
| 作者单位： | 陕西理工大学 化学与环境科学学院 陕西省催化基础与应用重点实验室,陕西 汉中,723001 |
| |
| 基金项目： | 陕西理工大学大学生创新创业培训计划项目 |
| |
| 摘 要： | 以1,3-双咪唑丙烷,3,5-吡啶二羧酸和Zn(NO_3)_2·6H_2O为原料,在水热条件下合成了一个新的Zn(Ⅱ)配合物{Zn(bbi)(3,5-pdc)]·2H_2O}n(1,bbi=1,3-二咪唑丙烷,3,5-pdc=3,5-吡啶二羧酸),其结构和热性能经IR,元素分析,X-射线单晶衍射和TGA表征。1属三斜晶系,P-1空间群,晶胞参数a=9.070 8(5)?,b=10.213 1(8)?,c=11.266 7(7)?,α=82.138(6)°,β=89.368(5)°,γ=75.419(6)°。室温固态荧光测试结果显示,在330 nm激发态下,1在424 nm具有强烈的荧光发射峰。
|
| 关 键 词： | 1 3-双咪唑丙烷 3 5-吡啶二羧酸 Zn(Ⅱ)配合物 合成 晶体结构 热重分析 荧光性质 |
Synthesis,Crystal Structure and Fluorescent Property of A Novel Zn(Ⅱ) Coordination Polymer Constructed by Pyridine-3,5-dicarboxylic Acid and Bisimidazole |
| |
| WANG Li,LI Shao-hua,WANG Rui-xue,LI Nan-nan,LIU Bin,YUAN Fen-fen,WANG Shuai,YAN Bin.Synthesis,Crystal Structure and Fluorescent Property of A Novel Zn(Ⅱ) Coordination Polymer Constructed by Pyridine-3,5-dicarboxylic Acid and Bisimidazole[J].Chinese Journal of Synthetic Chemistry,2017(1). |
| |
| Authors: | WANG Li LI Shao-hua WANG Rui-xue LI Nan-nan LIU Bin YUAN Fen-fen WANG Shuai YAN Bin |
| |
| Abstract: | A novel Zn(Ⅱ) coordination polymer, {Zn(bbi)(3,5-pdc)]·2H2O}n(1), was syn-thesized by hydrothermal method from 1,3-bis(imidazole)propane(bbi), pyridine-3,5-dicarboxylic acid(3,5-pdc) and zinc nitrate hexahydrate. The structure and thermal property were characterized by IR, elemental analysis, X-ray single crystal diffraction and TGA. The results showed that 1 belongs to triclinic system, space group P-1 with a=9. 0708(5)?, b=10. 213 1(8)?, c=11. 266 7(7) ?,α=82. 138(6)°,β=89. 368(5)°,γ=75. 419(6)°. Upon an excitation band at 330 nm, intense e-missions are observed at 421 nm for 1 in the solid state at room temperature. |
| |
| Keywords: | 1 3-bis( imidazole) propane pyridine-3 5-dicarboxylic acid Zn(Ⅱ) coordination poly-mer synthesis crystal structure thermogravimetric analysis fluorescent property |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
