| 可再生高价碘试剂4-二氯碘苯甲酸的合成及其氧化性能 |
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| 引用本文： | 魏孔祥,冯勇刚,王海龙.可再生高价碘试剂4-二氯碘苯甲酸的合成及其氧化性能[J].合成化学,2017,25(4). |
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| 作者姓名： | 魏孔祥 冯勇刚 王海龙 |
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| 作者单位： | 嘉兴学院生物与化学工程学院,浙江 嘉兴,314001 |
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| 摘 要： | 以对碘苯甲酸为原料,采用"一锅法"合成高价碘试剂4-二氯碘苯甲酸(1),其结构经~1H NMR和IR确证。考察了其对取代苯甲醇的氧化性能。结果表明:1对4-(二甲氨基)苄醇的氧化性能最高,收率93%。
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| 关 键 词： | 对碘苯甲酸 高价碘试剂 4-二氯碘苯甲酸 醇 氧化性能 应用 |
Preparation and Oxidizability of 4-(Dichloroiodo)benzoic Acidas A Recycle Hypervalent Iodine Regent |
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| WEI Kong-xiang,FENG Yong-gang,WANG Hai-long.Preparation and Oxidizability of 4-(Dichloroiodo)benzoic Acidas A Recycle Hypervalent Iodine Regent[J].Chinese Journal of Synthetic Chemistry,2017,25(4). |
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| Authors: | WEI Kong-xiang FENG Yong-gang WANG Hai-long |
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| Abstract: | Hypervalent iodine reagent, 4-(dichloroiodo) benzoic acid (1), was synthesized from 4-iodobenzoic acid through one-pot reaction.The structure was confirmed by 1H NMR and FT-IR.The oxidizability of 1 was investigated by the oxidation of substituted benzyl alcohol.The results showed that 1 exhibits higher oxidation efficiency for 4-(dimethyl amino) benzyl alcohol, and the yield was 93%. |
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| Keywords: | 4-iodobenzoic acid hypervalent iodine regent 4-(dichloroiodo) benzoic acid alcohol oxidizability application |
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