| 1,1,3,3-四甲基胍基衍生物的合成及其与二酸的分子识别性能研究 |
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| 引用本文： | 齐彦兴,高海翔,蔡利萍,杨敏,索继栓.1,1,3,3-四甲基胍基衍生物的合成及其与二酸的分子识别性能研究[J].合成化学,2004,12(2):103-107,110. |
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| 作者姓名： | 齐彦兴 高海翔 蔡利萍 杨敏 索继栓 |
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| 作者单位： | 1. 中国科学院兰州化学物理研究所,羰基合成与选择氧化国家重点实验室,甘肃,兰州,730000
2. 兰州大学化学系,应用有机化学国家重点实验室,甘肃,兰州,730000 |
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| 基金项目： | theNationalNaturalScienceFoundationofChina( 2 9873 0 62 ) |
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| 摘 要： | 四甲基胍分别与间苯二甲酰氯和间苯二磺酰氯反应合成了间苯二甲酰四甲基胍和间苯二磺酰四甲基胍,其结构经元素分析,IR,1H
NMR和EI-MS表征.核磁滴定研究表明,上述化合物可与二酸形成1 ∶1化学计量络合物,其络合常数在5.33×105～3.68×105.
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| 关 键 词： | 胍基衍生物 合成 分子识别 二酸 |
Synthesis and Molecular Recognition for Dicarboxylic Acid of 1,1,3,3-Tetramethyl Guanidine Derivatives |
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| Abstract.Synthesis and Molecular Recognition for Dicarboxylic Acid of 1,1,3,3-Tetramethyl Guanidine Derivatives[J].Chinese Journal of Synthetic Chemistry,2004,12(2):103-107,110. |
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| Authors: | Abstract |
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| Abstract: | 1,3-Di-{N-bis(dimethylamino)methene]}benzoyl-diamide and 1,3-di-{N-bis(dimethyl-amino)methane]}-benzoyl-disulfonamide were synthesized by the reaction of 1,1,3,3-tetramethyl-guanidine with isophthaloyl dichloride and 1,3-benzenedisulfonyl chloride separately. Their structures were confirmed by elementary analysis, IR, 1H NMR and EI-MS. 1H NMR titration indicated that 1 ∶1 stoichiometry complexes were formed between the guanidine derivative and dicarboxylic acids whose association constants range from 5.33 to 3.68×105. |
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| Keywords: | guanidine derivatives synthesis molecular recognition dicarboxylic acid |
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