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甲基环己基二氯硅烷合成工艺的研究
引用本文:张荣华,徐晶,李义久,朱志良,倪亚明.甲基环己基二氯硅烷合成工艺的研究[J].合成化学,2003,11(5):421-423.
作者姓名:张荣华  徐晶  李义久  朱志良  倪亚明
作者单位:同济大学化学系,上海,200092
摘    要:研究了在常压和无光照的情况下由环己烯和甲基二氯硅烷合成甲基环己基二氯硅烷的工艺,着重研究了合适的催化剂和助催化剂对氢硅加成反应的影响,并就反应液温度和反应时问对反应产物的影响进行色谱跟踪,研究显示反应过程可由反应液温度或反应时间来控制。该过程生产设备简单、操作简便、收率高。

关 键 词:甲基环己基二氯硅烷  氢硅加成反应  过程分析  合成工艺
文章编号:1005-1511(2003)05-0421-03
修稿时间:2002年11月7日

Synthesis Process of Cyclohexyl Methyl Dichlorosilane
ZHANG Rong hua,XU Jing,LI Yi jiu,ZHU Zhi liang,NI Ya ming.Synthesis Process of Cyclohexyl Methyl Dichlorosilane[J].Chinese Journal of Synthetic Chemistry,2003,11(5):421-423.
Authors:ZHANG Rong hua  XU Jing  LI Yi jiu  ZHU Zhi liang  NI Ya ming
Abstract:Cyclohexyl methyl dichlorosilane was prepared from cyclohexene and dichlorosilane under normal condition without high pressure and irradiation with valuable results. Meanwhile, the influence of catalyst and cocatalyst was studied and the need for the raw material was discussed. In order to improve the working efficiency, process analysis is employed based on gas chromatograph. Through process analysis the reaction can be controlled by the reaction temperature or reaction time. The restriction on the manufacture facilities and apparatuses can be relieved and productivity can be remarkably enhanced, which permit the decrease of the manufactory cost.
Keywords:cyclohexyl methyl dichlorosilane  hydrosilylation  process analysis  synthesis process
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