| 合成磷酰氯二烷基酯的新方法 |
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| 引用本文： | 陈志卫,王博,俞传明.合成磷酰氯二烷基酯的新方法[J].合成化学,2009,17(3). |
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| 作者姓名： | 陈志卫 王博 俞传明 |
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| 作者单位： | 浙江工业大学,药学院,浙江省制药工程重点实验室,浙江,杭州,310014 |
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| 基金项目： | 国家重点基础研究发展规划(973计划)，国家自然科学基金 |
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| 摘 要： | 以亚磷酸三烷基酯为原料,三氯异氰尿酸为氯代试剂,二氯甲烷为溶剂,在室温下合成了磷酰氯二烷基酯,其结构经1H NMR, 31P NMR和GC-MS确证.
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| 关 键 词： | 磷酰氯二烷基酯 亚磷酸三烷基酯 三氯异氰尿酸 合成 |
A New Method of Synthesizing Dialkyl Chlorophosphates |
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| CHEN Zhi-wei,WANG Bo,YU Chuan-ming.A New Method of Synthesizing Dialkyl Chlorophosphates[J].Chinese Journal of Synthetic Chemistry,2009,17(3). |
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| Authors: | CHEN Zhi-wei WANG Bo YU Chuan-ming |
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| Institution: | Zhejiang Key Laboratory of Pharmaceutical Engineering;College of Pharmaceutical Sciences;Zhejiang University of Technology;Hangzhou 310014;China |
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| Abstract: | Dialkyl chlorophosphates were synthesized form trialkyl phosphites using trichloroisocyanuric acid as a chlorinating reagent in dichloromethane at room temperature. The structures were confirmed by 1H NMR,31P NMR and GC-MS. |
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| Keywords: | dialkyl chlorophosphate trialkyl phosphate trichloroisocyanuric acid synthesis |
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