| 三氯一茂钛作用下的醛酮再生 |
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| 引用本文： | 严世强,陈宁.三氯一茂钛作用下的醛酮再生[J].合成化学,1996,4(2):184-186. |
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| 作者姓名： | 严世强 陈宁 |
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| 作者单位： | 兰州大学化学系 |
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| 摘 要： | 研究了ＣｐＴｉＣｌ３作用下２－苯基－１，３－二氧杂交戊烷转化的成苯甲醛的反应，在２－苯基－１，３－二氧杂环戊烷：ＣｐＴｉＣｌ３＝１：１反应温度３０℃，反应时间６ｈ的最佳条件下，缩醛的转化率达９６％，并讨论了不同醛，酮的再生结果以及ＫＩ对该转化反应和转化率的影响。
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| 关 键 词： | 三氯一茂钛 缩醛 缩酮 醛 酮 再生 |
Study on the Regeneration of Aldehydes and Ketonesin the Presence of CPTiCl_3 |
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| Yan,Shi-Qiang,Chen,Ning,Li,Jian-Jun,Zhang,Yu-Lan.Study on the Regeneration of Aldehydes and Ketonesin the Presence of CPTiCl_3[J].Chinese Journal of Synthetic Chemistry,1996,4(2):184-186. |
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| Authors: | Yan Shi-Qiang Chen Ning Li Jian-Jun Zhang Yu-Lan |
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| Abstract: | In our study on the reduction of acetal of benzaldehyde with ethylene glycol in the presence of CPTiCl_3,the best reactional condition has been found.Under such condition,the reductions of various acetals and ketals and the effect of KI to reduction are diseussed. |
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| Keywords: | s:CPTiCl_3 Acetal Ketal Aldehydes Ketones Regeneration |
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