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Adsorption of Brilliant Yellow onto Sepiolite: Evaluation of Thermodynamics and Kinetics and the Application of Nonlinear Isotherm Models
Authors:Nalan Tekin  Mine Aylin Bayrak  Emine Can
Institution:1. Faculty of Art and Science, Department of Chemistry, Kocaeli University, Kocaeli, Turkeynalan.tekin@kocaeli.edu.tr nalanisiktekin@gmail.com;3. Faculty of Art and Science, Department of Chemistry, Kocaeli University, Kocaeli, Turkey;4. Faculty of Science, Engineering Physics, Medeniyet University, Istanbul, Turkey
Abstract:We studied the adsorption of Brilliant Yellow (BY) from aqueous solutions onto sepiolite and determined the adsorption equilibrium isotherms. We applied pseudo-first-order and pseudo-second-order kinetic models; the adsorption of BY onto sepiolite was best described by the pseudo-second-order kinetic model. The experimental data obtained at different temperatures were analyzed using various isotherm models; the Koble–Corrigan isotherm model provided the best fits for the BY adsorption data at all temperatures. The thermodynamic parameters of the BY adsorption onto sepiolite indicated that the adsorption process is spontaneous and exothermic in nature.
Keywords:Adsorption  brilliant yellow  error analysis  isotherm  sepiolite
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