The Chemistry of 10-Pn-3 Systems1: Tricoordinate Hypervalent Pnictogen Compounds and Related Systems |
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| Authors: | Anthony J Arduengo III David A Dixon Constantine A Stewart |
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| Institution: | 1. E. I. Du Pont de Nemours &2. Company, Central Research and Development Department , Experimental Station , Wilmington, Delaware, 19898 |
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| Abstract: | Abstract The unusual hypervalent tricoordinate pnictogen systems, 10-Pn-3 ADPnO, provide a convenient starting point for the study of a wide range of main group chemistry. Differences in reactivity patterns among the pnictogens are readily apparent from the variety of chemistry exhibited. The ADPnO systems also provide a model for the recently recognized edge inversion mechanism for 3 and 4 coordinate 8-electron main group species. |
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