Polystyrene-supported phosphine oxide-catalysed Beckmann rearrangement of ketoximes in 1,1,1,3,3,3-hexafluoro-2-propanol |
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| Authors: | Yaoyao Wang Qun Chen |
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| Institution: | 1. School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials &2. Technology, Changzhou University, Changzhou, P. R. China |
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| Abstract: | A polystyrene-supported phosphine oxide-catalysed Beckmann rearrangement of ketoximes in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) has been developed. Good substrate compatibility, mild reaction conditions, good yields as well as the reusability of the catalyst/solvent made this procedure more environmentally benign. |
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| Keywords: | Supported phosphine oxide hexafluoroisopropanol Beckmann rearrangement ketoximes |
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