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Sigmatropic Rearrangements in Phosphorylated 2-Azaallylic Systems |
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| Authors: | P P Onys'ko T V Kim E I Kiseleva A D Sinytsa |
| Institution: | 1. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian;2. SSR , Kiev, 252660, USSR |
| Abstract: | Abstract Allylic and heteroallylic compounds are classical objects of organic chemistry and can serve as models in the investigation of various theoretical problems. The anions and 1,3-dipoles generated from azaallylic derivatives are widely used in the synthesis of cyclic and acyclic nitrogen-containing compounds. |
| Keywords: | Key words: dichlorocyclopropanation dihydrophosphole oxides diastereoisomers stereoselectivity X-ray analysis reactivity |