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A novel and convenient approach for tosyloxylation of aromatic ring of some ortho-substituted phenolic compounds using [hydroxy(tosyloxy)iodo]benzene
Authors:Om Prakash  Manoj Kumar
Institution:a Department of Chemistry, Kurukshetra University, Kurukshetra-136119, Haryana, India
b Post Graduate Department of Chemistry, M. L. N. College, Yamuna Nagar-135001, Haryana, India
Abstract:The oxidation of some substituted monohydric phenols, containing electron-withdrawing substituents at the ortho position to the phenolic group, with hydroxy(tosyloxy)iodo]benzene (HTIB, Koser’s reagent) leads to novel tosyloxylation of aromatic ring, thereby offering a convenient synthesis of hitherto unknown 4-tosyloxy-2-substituted phenols.
Keywords:Hypervalent iodine reagents  [Hydroxy(tosyloxy)iodo]benzene  Substituted phenols  Tosyloxylation
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