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Diversification of shotgun process
Authors:Yoshifumi NaganoAkihiro Orita  Junzo Otera
Institution:Department of Applied Chemistry, Okayama University of Science, Ridai-cho, Okayama 700-0005, Japan
Abstract:Three protocols for shotgun process are put forth in which simultaneous multi-fold reactions occur exclusively to each other. The first one involves simple combination of selective and non-selective reactions. Even if the simple protocol fails to give rise to the high selectivity, satisfactory outcome can be achieved by kinetic control or adjustment of functional groups.
Keywords:shotgun process  allylation  Diels-Alder reaction  acetylation  scandium triflate  ytterbium triflate
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