Tandem oxidative isocyanide-based cycloaddition reactions in the presence of MIL-101(Cr) as a reusable solid catalyst |
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Authors: | Ahmad Shaabani Heshmatollah Sepahvand Mostafa M Amini Alireza Hashemzadeh Mahmoud Borjian Boroujeni Elham Badali |
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Institution: | Faculty of Chemistry, Shahid Beheshti University, G. C., P. O. Box 19396-4716, Tehran, Iran |
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Abstract: | The tandem oxidative three-component synthesis of two types of the heterocycles such as furans and imidazopyridines, via isocyanides 1+4] cycloaddition reactions in the presence of MIL-101(Cr) under aerobic conditions are reported. When the 4-toluenesulfonylmethyl isocyanide was used, an unexpected 3+2] cycloaddition reaction of isocyanides with aldehydes accomplished and dihydrophenyloxazoles and phenyloxazoles produced. These syntheses were successfully carried out using a wide scope of the substrates. |
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Keywords: | Tandem oxidative Isocyanide Cycloaddition MIL-101(Cr) Aerobic oxidation |
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