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Gold(I)-catalysed iodoalkoxylation of allenes |
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| Authors: | Amelie Heuer-JungemannRoss G McLaren Maximillian S HadfieldAi-Lan Lee |
| Institution: | School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, United Kingdom |
| Abstract: | Gold(I)-catalysed intermolecular iodoalkoxylation of allenes occurs in a regioselective and stereoselective manner to produce versatile iodo-tert-allyllic ether products. The products can be further elaborated through cross-couplings to yield highly substituted tert-allylic ethers. |
| Keywords: | Gold catalysis Allenes Ethers Iodoalkoxylation |
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