Pd(II)-SPRIX catalyzed enantioselective construction of pyrrolizines/pyrroloindoles employing molecular oxygen as the sole oxidant |
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Authors: | Chennan Ramalingan Kazuhiro TakenakaHiroaki Sasai |
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Institution: | The Institute of Scientific and Industrial Research (ISIR), Osaka University, Mihogaoka, Ibaraki, Osaka 567-0047, Japan |
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Abstract: | Pd(II)-SPRIX catalyst coupled with an environmentally benign molecular oxygen as the sole oxidant successfully exploited the construction of pyrrolizines/pyrroloindoles, imperative scaffolds of bio-potent molecules through intramolecular C-N and C-C bond forming reactions in good yields with appreciable enantioselectivities. |
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Keywords: | Palladium Spiro bis(Isoxazoline) Enantioselectivity Molecular oxygen Pyrrolizines Pyrroloindoles |
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