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Synthesis of silica gel-bound acridino-18-crown-6 ether and preliminary studies on its metal ion selectivity
Authors:Júlia KertészPéter Huszthy  Attila KormosLászló Bezúr
Institution:a Research Group for Alkaloid Chemistry of the Hungarian Academy of Sciences, H-1521 Budapest, PO Box 91, Hungary
b Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, H-1521 Budapest, PO Box 91, Hungary
c Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, H-1521 Budapest, PO Box 91, Hungary
Abstract:Starting from commercially available and relatively cheap chemicals a novel silica gel-bound acridino-18-crown-6 ether was prepared. Selectivity of the latter stationary phase toward different metal ions was studied. The stationary phase showed appreciable selectivity for Ag+, Cu2+, and Hg2+ ions.
Keywords:Silica gel-bound crown ether  Acridine  Metal ion selectivity  Stationary phase
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