Organic synthesis by means of noble metal compound—LI : Palladium-catalyzed addition of butadiene to nitroalkanes |
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| Authors: | T Mitsuyasu J Tsuji |
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| Institution: | Basic Research Laboratories, Toray Industries, Inc., Kamakura, Japan |
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| Abstract: | Butadiene reacts with nitroalkanes in the presence of triphenylphosphine complexes of palladium, α-Hydrogens of nitroalkanes are displaced with 2,7-octadienyl groups to give nitroolefins. The nitroolefins thus obtained are reduced to give novel long chain amines, which have a primary amino group at the middle of the carbon chain. |
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