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Copper-mediated synthesis of α-trifluoromethylthio- and seleno-α,β-unsaturated carbonyl compounds
Authors:Peitao Zhu  Xing HeXiaoqing Chen  Yi YouYaofeng Yuan  Zhiqiang Weng
Institution:Department of Chemistry, Fuzhou University, Fujian 350108, China
Abstract:A novel route to the synthesis of α-trifluoromethylthio- and seleno-α,β-unsaturated carbonyl compounds via a copper-mediated trifluoromethylthiolation/trifluoromethylselenolation of α-halo-α,β-unsaturated carbonyl substrates is reported.
Keywords:Trifluoromethylthiolation  Trifluoromethylselenolation  α-Halo-α  β-unsaturated carbonyl compounds  Copper reagent
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