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Asymmetric 1,3-dipolar cycloadditions

Authors:	Hélène Pellissier [Author Vitae]

Institution:	UMR n° 6180, Université Paul Cézanne—Aix-Marseille III, Avenue Esc., Normandie-Niemen, 13397 Marseille Cedex 20, France

Abstract:

Keywords:	Ac acetyl All allyl Ar aryl Aux auxiliary BF₃· Et₂O boron trifluoride etherate BINAP 2 2&prime -bis(diphenylphosphanyl)-1 1&prime -binaphthyl BINOL 1 1&prime -bi-2-naphthol Bn benzyl Boc tert-butoxycarbonyl Born borneol Bz benzoyl Bu butyl Cbz benzyloxycarbonyl Cy cyclohexyl DBU 1 8-diazabicyclo[5 4 0]undec-7-ene DCE 1 2-dichloroethane de diastereomeric excess DEAD diethyl azodicarboxylate DIPT diisopropyl tartrate DMAD dimethyl acetylenedicarboxylate DMF dimethylformamide dr diastereomeric ratio E electrophile ee enantiomeric excess Et ethyl Fe ferrocenyl Fu furyl Hex hexyl HMDS hexamethyldisilazide HMPA hexamethylphosphoramide L ligand LDA lithium diisopropylamide LHMDS lithium hexamethyldisilazide M metal MAPh methylaluminium bis(2 6-diphenylphenoxide) Me methyl MPM 4-methoxyphenylmethyl Ms mesyl MOM methoxymethyl Np naphthyl Pent pentyl Ph phenyl Piv pivaloyl PMB p-methoxybenzoyl PMP p-methoxyphenyl Pr propyl p-TSA p-toluenesulfonic acid Py pyridyl SEM [2-(trimethylsilyl)ethoxy]methyl TBAT tetrabutylammonium triphenyldifluorosilicate TBDMS tert-butyldimethylsilyl TBDPS tert-butyldiphenylsilyl TES triethylsilyl Tf trifluoromethanesulfonyl TFA trifluoroacetic acid THF tetrahydrofuran THP tetrahydropyranyl TIPS triisopropylsilyl TMS trimethylsilyl Tol tolyl TPP tetraphenylporphyrin Ts 4-toluenesulfonyl (tosyl)
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