Laboratory and field measurements of a badge type passive sampler for the determination of ambient sulfur dioxide concentrations |
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Authors: | Anne Kasper-Giebl S Krenn H Puxbaum |
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Institution: | (1) Institute for Analytical Chemistry, Vienna University of Technology, Getreidemarkt 9/151, A 1060 Vienna, Austria, AT |
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Abstract: | The performance of a badge type passive sampler for the determination of sulfur dioxide is described. The trapping agent
is triethanolamine. Analysis is performed by ion chromatography. Thus, the method allows the simultaneous detection of sulfur
dioxide and nitrogen dioxide. The sampler was tested in the laboratory and in the field. The intercomparison with independent
methods in the field showed very good agreement against two active sampling methods. Regression analyses (the results of the
passive sampler always represent the y-axes) gave r2 = 0.81 and k = 1.07 ± 0.01 for the intercomparison with an annular denuder technique and r2 = 0.92 and k = 0.96 ± 0.01 for the intercomparison with a commercial fluorescence sulfur dioxide analyzer. The average reproducibility
in the field was 7% (RSD). The detection limit was 0.18 μg SO2/m3 for an exposure time of two weeks.
Received: 9 February 1998 / Revised: 22 June 1998 / Accepted: 26 June 1998 |
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