High Stokes shift long-wavelength energy gap regulated fluorescence in the series of nitro/dimethylamino-substituted ortho-analogs of POPOP |
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Authors: | Rodion Yu Iliashenko Olexiy S Zozulia Andrey O Doroshenko |
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Institution: | (1) Department of Chemistry, Faculty of Science, Taibah University, Al-MAdinah Al-Munawarah, P.O. Box 30002, Kingdom of Saudi Arabia |
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Abstract: | A series of novel nitro-substituted ortho-analogs of POPOP was synthesized. Like the most of the other known compounds of this class, the synthesized molecules demonstrate
high Stokes shift fluorescence emission owing to the planarization of their molecules at electronic excitation. Significant
fluorescence quenching in polar solvents was described as the “energy gap law” action rather than the specific effect of the
dialkylamino group excited state twisting.
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