Intercalation of non-aromatic heterocyclic amines into layered zirconium glycine-<Emphasis Type="Italic">N,N</Emphasis>-dimethylphosphonate |
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Authors: | Xin Bin Yang Xiang-Kai Fu Ren-Quan Zeng |
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Institution: | (1) The Key Laboratory of Global Change and Marine-Atmospheric Chemistry, Third Institute of Oceanography of State Oceanic Administration, Xiamen, 361005, China;(2) College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China |
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Abstract: | New materials were prepared by intercalation reactions between layered zirconium glycine-N,N-dimethylphosphonate (ZGDMP) and non-aromatic heterocyclic amines: piperazine, piperidine, and morpholine. X-ray powder diffraction
patterns showed that the entrance of piperazine, piperidine, and morpholine caused an interlayer expansion of 0.40 nm, 0.66
nm, and 0.67 nm, respectively. The infrared spectra were in agreement with an acid-base reaction, involving layered acid host
COOH of ZGDMP and basic center atoms of guest molecules. Thermogravimetric curves revealed thermal stability of the intercalation
compounds and content of the inserted amine molecules. These results indicate that non-aromatic heterocyclic amines were intercalated
into the galleries of host ZGDMP. |
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Keywords: | |
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