用毛细管色谱法分析14种拟除虫菊酯立体异构体

用石英毛细管柱分离了14种拟菊酯的立体异构体。柱1用QF-1固定液10m×0.53mm×1.0μm膜厚，柱温在180℃～260℃之间，可完全分离右旋丙炔菊酯等10种拟菊酯的立体异构体。往2为HP-525m×0.53mm×1.0μm膜厚，用合适的住温可分离百治菊酯等4种拟菊酯的异构体。

Analysis of the Stereoisomers of 14 Pyrethroids by Capillary Gas Chromatography

The separation of stereoisomers of 14 pyrethroids has been studied by capillary gas chromatography. The pyrethroids are cypermethrin (P1), phenothrin (P2), allethrin (P3), prallethrin (P4), tetramethrin (P5), permethrin (P6), cyfluthrin (P7), fenvalerate (P8), flucythrinate (P9), bromofenvalerate (P10), fluvalinate (P11), methothrin (P12), resmethrin (P13) and py115 (P14). The gas chromatographic conditions were as follows. Column 1: fused silica, 10m x 0.53mm x 1.0microm film (QF-1); columntemperature: 180 degrees C-260 degrees C depending on the pyrethroids analysed; the temperature of injector and detector: 280 degrees C; carrier gas: H2 4.6mL/min; detector: FID; spilt ratio: 5:1, sample size 1.0 L. The stereoisomers of P2, P3, P4, P5, P6, P8, P9, P10, P12 and P10 can be completely separated by QF-1 column. However the stereoisomers of P11 can not be separated and the three peaks of P1 and P7 have been only separated by column 1. In comparing with packed column of QF-1, there are advantages in superior resolution, lower oven temperature and shorter analysis time for capillary column of QF-1. Column 2: fused silica HP-5 (crosslinked 5% phenyl methyl silicone) 25m x 0.32mm x 1.0microm film; column temperature: P1 and P7 250 degrees C, P11 260 degrees C, and P14 200 degrees C; carrier gas: H2 2.6mL/min. Other conditions were the same as the column 1 described. The stereoisomers of P1, P7, P11 and P14 can be separated, but the separation of stereoisomers was not sufficient. The stereoisomers of P2, P5, P6, P8, P9, P10, P12 and P13 can be completely separated by HP-5 capillary column. However separation on the HP-5 capillary column is not sufficient for diastereoisomers of P3 and P4.