| 树状大分子接枝型聚合物色谱分离材料研究进展 |
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| 引用本文： | 支明玉,何艺,郭丹丹,朱岩.树状大分子接枝型聚合物色谱分离材料研究进展[J].色谱,2020,38(4):366-371. |
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| 作者姓名： | 支明玉 何艺 郭丹丹 朱岩 |
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| 作者单位： | 1. 浙江大学西溪校区化学系,浙江 杭州 3100282. 杭州职业技术学院,浙江 杭州 3100183. 宁波大学新药技术研究院,浙江 宁波 315211 |
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| 基金项目： | 国家自然科学基金(21974121);浙江省自然科学基金(LY18C200001);浙江省自然科学基金(YB19B050002);浙江省自然科学基金(Z16B050001) |
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| 摘 要： | 随着色谱固定相制备技术和材料科学领域的不断发展,目前已经有大量修饰方法和新型材料被用于固相萃取、高效液相色谱以及离子色谱聚合物固定相填料的功能化修饰。其中聚酰胺-胺(PAMAM)树状大分子由于其独特的结构和性质,在色谱分离材料结构完善和性能提升中也发挥了重要的作用。该文主要综述了PAMAM树状大分子在以聚合物为基质的色谱分离材料修饰中的应用,并对其今后的发展进行了展望。
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| 关 键 词： | 树状大分子 聚合物基质 吸附剂 液相色谱 离子色谱 |
| 收稿时间： | 2019-08-06 |
Advances in polymer-based dendrimer-grafted chromatographic separation materials |
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| ZHI Mingyu,HE Yi,GUO Dandan,ZHU Yan.Advances in polymer-based dendrimer-grafted chromatographic separation materials[J].Chinese Journal of Chromatography,2020,38(4):366-371. |
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| Authors: | ZHI Mingyu HE Yi GUO Dandan ZHU Yan |
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| Institution: | 1. Department of Chemistry, Xixi Campus, Zhejiang University, Hangzhou 310028, China2. Hangzhou Vocational and Technical College, Hangzhou 310018, China3. Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, China |
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| Abstract: | With the continuous developments in stationary phase preparation technology and materials science, numerous modification methods and new materials have been employed for the functional modification of the polymer stationary phases in solid-phase extraction, high performance liquid chromatography and ion chromatography. In particular, because of their unique structure and properties, poly(amidoamine) (PAMAM) dendrimers play an important role in improving the structure and performance of chromatographic separation materials. In this paper, the application of PAMAM to the modification of polymer-based chromatographic separation materials is reviewed, and further developments are prospected. |
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| Keywords: | dendrimers polymer matrix adsorbent liquid chromatography ion chromatography |
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