Silver-catalyzed decarboxylative homocoupling reaction for the construction of tetrafluoroethylene-bridging aromatic compounds |
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| Authors: | Yong Wang Huaxin Zhao Xiaojuan Xie Haizhen Jiang Hongmei Deng |
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| Institution: | 1. Department of Chemistry, Shanghai University, Shanghai, China;2. Laboratory of Microstructures, Shanghai University, Shanghai, China |
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| Abstract: | The Ag(I)-catalyzed decarboxylative homocoupling from the difluoroacetate has been developed to the synthesis of symmetric CF2–CF2 containing dimers. This radical dimerization overpasses the prefunctionalization of the substrate and provides a direct and efficient method for construction of tetrafluoroethylene bridge-linked homodimers. |
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| Keywords: | Decarboxylative homocoupling difluoroacetate radical dimerization tetrafluoroethylene bridge |
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