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Novel and Efficient Oxidation of Benzyl Ethers to Benzaldehydes by DMSO/49% Aq. HBr
Authors:Ramesh Naik
Institution:Department of Chemistry , Central College Campus, Bangalore University , Bangalore, India
Abstract:Dimethylsulfoxide (DMSO) oxidizes benzyl ethers into corresponding benzaldehydes at 110°C; the reaction is accelerated by 49% aq. HBr. The conditions work well for different aryl‐substituted benzyl ethers. This protocol is inert toward dialkyl ethers.
Keywords:benzaldehydes  benzyl ethers  DMSO/49% aq  HBr
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