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Reaction of bis-Lactone in Rigid Polycycles with Alkyl Lithiums. Synthesis of Novel Oxa-Cace Compounds |
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| Authors: | Subrata Sarkar Subrata Ghosh |
| Institution: | Department of Organic Chemistry , Indian Association for the Cultivation of Science , Jadavpur, Calcutta, 700 032, India |
| Abstract: | Reaction of bis-lactone embodied in the rigid tircyclo 5.2.1.02,6] decane 5 with MeLi and t-BuLi produced the novel oxa-cage compounds 9 and 11 instead of the expected ketones 6. |
| Keywords: | |