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Temperature-controlled change of charge transport mechanisms in nonionic water-in-oil microemulsions
Authors:Hans-Friedrich Eicke  Holger Hammerich
Institution:Institut für Physikalische Chemie Dept. Chemie, Universit?t Basel 4056 Basel, Switzerland e-mail: hans-friedrich.eicke@unibas.ch, CH
Abstract: The temperature-controlled transition from the Stokes charge transport of aqueous nanodroplets to the intrinsic conduction of nanodroplet clusters in nonionic microemulsions was studied. Two different charge transport processes apparent from a minimum value of the conductance have been simulated based on straightforward physical models. Their predictions compare favourably with the observations. Received: 4 September 2001 Accepted: 20 September 2001
Keywords:  Nonionic pentaethylene glycol monoalkyl ethers  Water-in-oil microemulsions with added electrolyte  Charge transport processes  Temperature dependence of transport mechanisms  Modelling of transport mechanisms
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