Viscosity Mixing Rules for Binary Systems Containing One Ionic Liquid |
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| Authors: | Dr Mohammed Tariq Dr Daniel Salavera Prof Alberto Coronas Prof Luis P N Rebelo Prof Jose N Canongia Lopes |
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| Institution: | 1. Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Av. Da Republica, 2780‐157 Oeiras (Portugal) www.itqb.unl.ptEqual contributions;2. CREVER—Group of Applied Thermal Engineering, Department of Mechanical Engineering, Universitat Rovira i Virgili, Av. Pa?sos Catalans 26, 43007 Tarragona (Spain);3. Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Av. Da Republica, 2780‐157 Oeiras (Portugal) www.itqb.unl.pt;4. Centro de Química Estrutural, Instituto Superior Tecnico, 1049‐001 Lisboa (Portugal) |
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| Abstract: | In this work the applicability of four of the most commonly used viscosity mixing rules to ionic liquid (IL)+molecular solvent (MS)] systems is assessed. More than one hundred (IL+MS) binary mixtures were selected from the literature to test the viscosity mixing rules proposed by 1) Hind (Hi), 2) Grunberg and Nissan (G–N), 3) Herric (He) and 4) Katti and Chaudhri (K–C). The analyses were performed by estimating the average (absolute or relative) deviations, AADs and ARDs, between the available experimental data and the predicted ideal mixture viscosity values obtained by means of each rule. The interaction terms corresponding to the adjustable parameters inherent to each rule were also calculated and their trends discussed. |
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| Keywords: | binary mixtures ionic liquids mixing rules modelling viscosity |
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