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Adsorption isotherm of CO on Pt(111) electrodes.
Authors:Angel Cuesta  María del Carmen Pérez  Alejandro Rincón  Claudio Gutiérrez
Institution:Instituto de Química Física Rocasolano, CSIC, C. Serrano, 119, E-28006 Madrid, Spain. a.cuesta@iqfr.csic.es
Abstract:We have determined, for the first time, the equilibrium CO coverage of Pt(111) electrodes at room temperature in 0.1 M H(2)SO(4) as a function of the CO partial pressure using CO-stripping cyclic voltammetry. Fourier-transform infrared (FT-IR) spectroscopy was used to confirm qualitatively the coverage values obtained.
Keywords:adsorption isotherm  carbon monoxide  chemisorption  electrochemistry  platinum
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