| 有机硅反应活性中间体的研究I:光化学方法产生含呋喃环硅烯 |
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| 引用本文： | 吴世晖,武戈,陶凤岗,林子森.有机硅反应活性中间体的研究I:光化学方法产生含呋喃环硅烯[J].化学学报,1987,45(11):1107-1111. |
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| 作者姓名： | 吴世晖 武戈 陶凤岗 林子森 |
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| 作者单位： | 复旦大学化学系 |
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| 摘 要： | 2-(α-呋喃基)-2-苯基六甲基三硅烷在光照下可产生新型的有机硅活性中间体-α-呋喃基苯基硅烯.它与2,3-二甲基-1,3-丁二烯反应后,得到了相应的加成与插入反应产物;与环己烯反应后,再用甲醇分解所得硅杂环丙烷中间物得到了α-呋喃基环己基苯基甲氧基硅烷.
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| 关 键 词： | 光化学反应 苯P 环己烷P 呋喃P 呋喃P 有机硅化合物 硅烷P 环己烯 丁二烯P 硅烯 |
Studies on the organosilicon reactive intermediates I: Generation of furylphenylsilylene by photochemical method |
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| WU SHIHUI,WU GE,TAO FENGGANG,LIN ZISEN.Studies on the organosilicon reactive intermediates I: Generation of furylphenylsilylene by photochemical method[J].Acta Chimica Sinica,1987,45(11):1107-1111. |
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| Authors: | WU SHIHUI WU GE TAO FENGGANG LIN ZISEN |
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| Abstract: | a-Furylphenylsilylene was generated by the photolysis of 2-(a-furyl)-2-phenylhexamethyltrisilane. When a a-furylphenylsilylene reacted with 2,3-dimethyl-1,3-butadiene, the expected addition and insertion reaction products I and II were obtained. The intermediate silirane derivative resulted from the reaction of a-furylphenylsilylene with cyclohexene was decomposed by methanol to give a-furylphenylcyclohexylmethoxysilane. |
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| Keywords: | PHOTOCHEMICAL REACTION BENZENE P CYCLOHEXANE P FURAN P FURAN P ORGANO SILICON COMPOUNDS SILANE P CYCLOHEXENE BUTADIENE P SILYLENE |
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