| 杯芳烃的超分子化学研究（IV）：对-叔丁基杯[4]芳烃对ATP的分子识别及液膜传输作用 |
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| 引用本文： | 刘宇,陶雅秋,曹炎炎,梁剑,顾金英,施宪法.杯芳烃的超分子化学研究（IV）：对-叔丁基杯[4]芳烃对ATP的分子识别及液膜传输作用[J].化学学报,2002,60(6):1111-1115. |
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| 作者姓名： | 刘宇 陶雅秋 曹炎炎 梁剑 顾金英 施宪法 |
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| 作者单位： | 同济大学化学系.上海(200092) |
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| 基金项目： | 国家自然科学基金(No.29971023)资助项目. |
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| 摘 要： | 采用气泡式准乳化液膜法，研究了对-叔丁基杯4]芳烃对ATP分子的液膜传输 作用，讨论了源相与吸收相的组成、酸度、源相中的ATP的起始浓度及吸收相中 NH_3·H_2O浓度等因素对传输结果的影响；进而讨论了对-叔丁基杯4]芳烃对ATP 的分子识别作用和液膜传输机理。
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| 关 键 词： | 杯芳烃 液膜技术 |
| 修稿时间： | 2001年10月12 |
Study on Supramolecular Chemistry of Calixarene (IV): Liquid Membrane Transport and Molecular Recognition to ATP by p-tert- butylcalix[4]arene |
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| Liu Yu,Tao Yaqiu,Cao Yanyan,Liang Jian,Gu Jinying,Shi Xianfa.Study on Supramolecular Chemistry of Calixarene (IV): Liquid Membrane Transport and Molecular Recognition to ATP by p-tert- butylcalix[4]arene[J].Acta Chimica Sinica,2002,60(6):1111-1115. |
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| Authors: | Liu Yu Tao Yaqiu Cao Yanyan Liang Jian Gu Jinying Shi Xianfa |
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| Institution: | Department of Chemistry, Tongji University.Shanghai(200092) |
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| Abstract: | The liquid membrane transport of adenosine-5'-triphosphate (ATP) with p-tert-butylcalix4]arene as carrier has been investigated by means of a bubbling pseudo-emulsion liquid membrane system. The effects of the compositions, acidity of source phase or receiving phase, and the concentrations of ATP and NH_3·H_2O in source phase or receiving phase on the transport were studied. The molecular recognition of p-tert-butylcalix4]arene to ATP and the mechanism of liquid membrane transport were discussed. |
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| Keywords: | ATP |
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