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| α-蒎烯含氮衍生物的合成及其杀松材线虫活性的研究 | |
| 引用本文： | 杨益琴,王石发,李艳苹,袁冬菊,赵博光,谷文,叶建仁.α-蒎烯含氮衍生物的合成及其杀松材线虫活性的研究[J].化学学报,2009,67(21):2463-2474. |
| 作者姓名： | 杨益琴 王石发 李艳苹 袁冬菊 赵博光 谷文 叶建仁 |
| 作者单位： | 1. 南京林业大学轻工科学与工程学院 南京 210037 2. 南京林业大学化学工程学院 南京 210037 3. 南京林业大学森林资源与环境学院 南京 210037 4. 江苏省有害生物入侵预防与控制重点实验室 南京 210037 |
| 基金项目： | 国家自然科学基金，国家自然科学基金重点项目，江苏省有害生物入侵预防与控制重点实验室开放基金 |
| 摘 要： | <以α-蒎烯为原料, 经硼氢化-氧化、胺化及选择性还原等步骤合成了系列3-蒎酮亚胺和3-蒎胺类化合物, 探索了3-蒎酮亚胺和3-蒎胺的不同结构与杀松材线虫活性的关系. 采用FT-IR, 1H NMR, 13C NMR, GC-MS等分析手段对蒎酮亚胺和蒎胺类化合物的结构进行了表征. 结果表明: N-苯基-3-蒎酮亚胺具有很强的杀松材线虫活性, 在1×10－3 µL/mL (约1×10－3 mg/mL) 浓度下, 在24, 48和72 h内杀线虫效率分别达到89.28%, 89.58%和95.75%, 该化合物极具开发潜力. |
| 关 键 词： | α-蒎烯 α-蒎烯含氮衍生物 松材线虫 杀线虫活性 |
| 收稿时间： | 2008-10-04 |
| 修稿时间： | 2009-01-20 |
Synthesis of Nitrogen-Containing Derivatives from α-Pinene and Their Nematicidal Activity against Pinewood Nematode |
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| Yang Yiqin,Wang Shifa,Li Yanping,Yuan Dongju,Zhao Boguang,Gu Wen,Ye Jianren.Synthesis of Nitrogen-Containing Derivatives from α-Pinene and Their Nematicidal Activity against Pinewood Nematode[J].Acta Chimica Sinica,2009,67(21):2463-2474. | |
| Authors: | Yang Yiqin Wang Shifa Li Yanping Yuan Dongju Zhao Boguang Gu Wen Ye Jianren |
| Institution: | ( College of Light Industry and Engineering, Nanjing Forestry University, Nanjing 210037) ( College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037) ( College of Forest Resources and Environment, Nanjing Forestry University, Nanjing 210037) ( Jiangsu Provincial Key Laboratory for Prevention and Management of Invasive Species, Nanjing 210037) |
| Abstract: | A series of imine and amine derivatives were synthesized from a-pinene by hydroboronation, oxidation, amination, and selective reduction. The nematicidal activities of 3-pinanimines and 3-pinanamines were examined by the bioassay. Furthermore, the chemical structures of synthesized imines and amines were characterized based on FT-IR, ~1H NMR, ~(13)C NMR and GC-MS. The bioassay results showed that N-phenyl-3-pinanimine had the strongest nematicidal activity and it is very possible to commer-cialize because its nematicidal effects after 24, 48, and 72 h reached 89.28%, 89.58% and 95.75%, respec-tively when the level of N-phenyl-3-pinanimine was 1× 10~(-3)μL/mL (about 1 ×10~(-3) mg/mL). |
| Keywords: | nitrogen-containing pinene derivative pinewood nematode nematicidal activity |
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