| 新型阴离子表面活性剂的合成及其反胶束体系的酶催化性能 |
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| 引用本文： | 刘景林,林毅,褚莹,吕忠贤,吴子生.新型阴离子表面活性剂的合成及其反胶束体系的酶催化性能[J].化学学报,2004,62(20):1998-2002,F006. |
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| 作者姓名： | 刘景林 林毅 褚莹 吕忠贤 吴子生 |
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| 作者单位： | 东北师范大学化学学院,长春,130024 |
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| 基金项目： | 东北师范大学自然科学基金 (No.1 1 1 378)资助项目 |
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| 摘 要： | 合成了未见文献报道的新型阴离子表面活性剂磷酸二(2-乙基己氧基)乙基]酯钠(sodium di-(2-ethylhexyloxy)ethyl] phosphate，DEEPA)；以核磁共振氢谱和红外光谱表征了它的结构；在DEEPK/异辛烷反胶束体系中进行了脂肪酶催化橄榄油水解反应实验.结果表明，该反胶束体系的催化活性优于AOT反胶束体系，更优于油-水双相中的酶催化反应，最大活性是油-水双相体系的1.86倍.
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| 关 键 词： | 阴离子表面活性剂 合成 反胶束体系 酶催化性能 |
Synthesis of a New Anionic Surfactant and Catalytic Performance of Lipase in Its Reversed Micelles |
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| LIU,Jing-Lin,LIN,Yi,CHU,Ying,L,Zhong-Xian,WU,Zi-Sheng.Synthesis of a New Anionic Surfactant and Catalytic Performance of Lipase in Its Reversed Micelles[J].Acta Chimica Sinica,2004,62(20):1998-2002,F006. |
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| Authors: | LIU Jing-Lin LIN Yi CHU Ying L Zhong-Xian WU Zi-Sheng |
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| Institution: | LIU,Jing-Lin,LIN,Yi,CHU,Ying,L(U),Zhong-Xian,WU,Zi-Sheng |
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| Abstract: | A new anionic surfactant that has never been reported before, sodium (di-(2-ethylhexyloxy)ethyl]) phosphate (DEEPA), has been synthesized. Its structure has been characterized with ()~1H NMR and FT-IR spectrum. Hydrolysis of olive oil catalyzed by lipase using reversed micelle composed of DEEPA and isooctane was carried out. The results show that the catalytic performance of DEEPA reversed micelle is superior to that of AOT reversed micelle, and more superior to that of oil-water double phased system. |
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| Keywords: | surfactant synthesis reversed micelle enzyme catalysis |
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