| meso-四(邻烷氧基苯基)卟啉及其铜配合物的合成、表征和性能研究 |
| |
| 引用本文： | 赵鸿斌,罗和安,贺江平,彭圣明,谢琼玉.meso-四(邻烷氧基苯基)卟啉及其铜配合物的合成、表征和性能研究[J].化学学报,2006,64(4):331-337. |
| |
| 作者姓名： | 赵鸿斌 罗和安 贺江平 彭圣明 谢琼玉 |
| |
| 作者单位： | 湘潭大学化学化工学院,湘潭,411105 |
| |
| 基金项目： | 湖南省自然科学基金(Nos04JJ40013,01JJY2046)，湖南省教育厅科技基金(No00C074)资助项目 |
| |
| 摘 要： | 合成了meso-四(邻烷氧基苯基)卟啉及其铜配合物两个系列20个化合物, 其中未见文献报道的化合物16个, 研究了其合成、分离、纯化方法, 得到了这两个系列化合物的晶体或固体, 用1H NMR, MS, IR, UV, 元素分析等方法确证了这些化合物的结构. 用差示扫描量热法(DSC)和偏光显微镜(PM)研究了这两个系列化合物的液晶性能, 发现19个化合物具有液晶性, 其液晶行为表现为升温单变液晶.
|
| 关 键 词： | meso-四(邻烷氧基苯基)卟啉 卟啉铜配合物 合成 表征 液晶性 |
| 收稿时间： | 07 21 2005 12:00AM |
| 修稿时间： | 2005-07-212005-10-17 |
Synthesis, Characterization and Properties of meso-Tetrakis(2-alkoxyphenyl)porphyrins and Their Copper(II) Complexes |
| |
| ZHAO Hong-Bin,LUO He-An,HE Jiang-Ping,PENG Sheng-Ming,XIE Qiong-Yu.Synthesis, Characterization and Properties of meso-Tetrakis(2-alkoxyphenyl)porphyrins and Their Copper(II) Complexes[J].Acta Chimica Sinica,2006,64(4):331-337. |
| |
| Authors: | ZHAO Hong-Bin LUO He-An HE Jiang-Ping PENG Sheng-Ming XIE Qiong-Yu |
| |
| Institution: | College of Chemistry and Chemical Engineering, Xiangtan University, Xiangtan 411105 |
| |
| Abstract: | A series of meso-tetrakis(2-alkoxyphenyl)porphyrin derivatives (ROPh)4PH2] and their cop-per(II) complexes (ROPh)4PCu] were synthesized, and sixteen of them were new compounds. For the first time, (ROPh)4PH2] and (ROPh)4PCu] were generated as crystals or solids. The 1H NMR, mass, FTIR, UV-Vis spectra and elemental analysis data were in good agreement with the assigned structures. The liquid crystalline (LC) properties of twenty compounds were studied by differential scanning calorimetry and po-larizing microscope. It was observed that nineteen of them behaved as LC in a wide range of temperature. However, they displayed as heated monotropic liquid crystals. |
| |
| Keywords: | meso-tetrakis(2-alkoxyphenyl)porphyrin copper complex of porphyrin synthesis characteri-zation liquid crystal property |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《化学学报》浏览原始摘要信息 |
| 点击此处可从《化学学报》下载免费的PDF全文 |
|
