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| 应用ICP消解氟里昂的优越性及其处理效率的初步研究 | |
| 引用本文： | 陈登云,王小如,贺红军,周炜,蔡启欣,Frank.S.C.LEE.应用ICP消解氟里昂的优越性及其处理效率的初步研究[J].化学学报,1999,57(10):1136-1141. |
| 作者姓名： | 陈登云 王小如 贺红军 周炜 蔡启欣 Frank.S.C.LEE |
| 作者单位： | 1. 教育部材料与生命过程分析科学开放实验室,厦门大学化学系,厦门,361005 2. 厦门市环保局杏林环境监测站,厦门,361000 3. 香港浸会大学化学系,香港九龙塘 |
| 基金项目： | 国家自然科学基金(29421006)，优秀中青年人才专项基金，国家教委博士点基金资助项目 |
| 摘 要： | 讨论了应用高频电感耦合等离子体(ICP)消解氟里昂类废弃物的可行性及与国际先进技术的比较;应用低功率ICP系统进行氟里昂12的模拟消解,用GC-ECD方法对尾气中的残余成分和浓度进行分析,证明该系统对氟里昂12的处理效率高于99.9%,可以发展成为未来环保废物处理领域的一项新技术。 |
| 关 键 词： | 电感耦合等离子体 废物处理 氟里昂 消解 |
| 修稿时间： | 1998年9月28日 |
The primary study of freon 12 destruction efficiency and advantages of the inductively coupled plasma (ICP) system |
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| CHEN Deng-Yun,WANG Xiao-Ru,HE Hong-Jun,ZHOU Wei,CAI Qi-Xin,Frank.S.C.LEE.The primary study of freon 12 destruction efficiency and advantages of the inductively coupled plasma (ICP) system[J].Acta Chimica Sinica,1999,57(10):1136-1141. | |
| Authors: | CHEN Deng-Yun WANG Xiao-Ru HE Hong-Jun ZHOU Wei CAI Qi-Xin FrankSCLEE |
| Institution: | Xiamen Univ, Dept Chem.Xiamen(361005) |
| Abstract: | An inductively coupled plasma (ICP) system used for the destruction of Freon wastes has been discussed and compared with the advanced foreign technology used for the destruction of hazardous wastes. The advantages of the ICP technology and its possibility to be developed into a practical environmental protection technology are also discussed. The exhaust gas from the ICP system is sampled and analyzed by GC-ECD method. Phosgene and trace amounts of CF2Cl2, CHCl3, CH2Cl2, CCl4 etc. are identified quantitatively. The total destruction efficiency of the ICP system for Freon 12 is calculated to be more than 99.9%. |
| Keywords: | inductively coupled plasma (ICP) waste management Freon 12 GC-ECD |
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