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聚异丁烯丁二酰亚胺系列衍生物的合成及其对TiO2纳米粒子的分散性能研究
引用本文:戴树洌,施敏敏,Hamf,Muddasir,刘胜,陈红征.聚异丁烯丁二酰亚胺系列衍生物的合成及其对TiO2纳米粒子的分散性能研究[J].化学学报,2011,69(20):2373-2378.
作者姓名:戴树洌  施敏敏  Hamf  Muddasir  刘胜  陈红征
作者单位:高分子合成与功能构造教育部重点实验室硅材料国家重点实验室浙江大学高分子科学与工程学系,杭州,310027
基金项目:国家高技术研究发展计划(No.2008AA03A331); 国家自然科学基金(Nos.51073135,50990063,51011130028)资助项目
摘    要:合成了含有确定长度的聚异丁烯链段与4种不同的乙烯胺链段(乙二胺、二乙烯三胺、三乙烯四胺和四乙烯五胺)组合的聚异丁烯丁二酰亚胺系列衍生物,并将它们用作TiO2纳米粒子在非极性溶剂中的分散剂.详细考察了亲水/亲油基团大小对分散性能的影响规律:当聚异丁烯链段的分子量为2000时,随着乙烯胺段链长的增加,TiO2粒子的粒径和Z...

关 键 词:聚异丁烯丁二酰亚胺  TiO2纳米粒子  分散性能  HLB值  电泳显示

Polyisobutenylsuccinimide Derivatives: Synthesis and Their Application in the Dispersing of TiO_2 Nanoparticles
Dai,Shulie Shi,Minmin Hanif,Muddasir Liu,Sheng Chen,Hongzheng.Polyisobutenylsuccinimide Derivatives: Synthesis and Their Application in the Dispersing of TiO_2 Nanoparticles[J].Acta Chimica Sinica,2011,69(20):2373-2378.
Authors:Dai  Shulie Shi  Minmin Hanif  Muddasir Liu  Sheng Chen  Hongzheng
Institution:Dai,Shulie Shi,Minmin Hanif,Muddasir Liu,Sheng Chen,Hongzheng(Key Laboratory of Macromolecule Synthesis and Functionalization,Ministry of Education,State Key Laboratory of Silicon Materials,Department of Polymer Science and Engineering,Zhejiang University,Hangzhou 310027)
Abstract:A series of polyisobutenylsuccinimide derivatives,in which polyisobutenylene block with a definite chain length was linked with four different ethylenediamine end groups(diaminoethane,diethylenetriamine,triethylenetetraamine,and tetraethylenepentaamine),were synthesized and used to dis-perse TiO2 nanoparticles in nonpolar solvent.The influences of the sizes of hydrophilic/hydrophobic groups on the dispersibility of TiO2 nanoparticles were investigated,and it was found that: when the molecular weight of poly...
Keywords:polyisobutenylsuccinimide  TiO2 nanoparticles  dispersibility  HLB value  electrophoretic dis-play  
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